|
|
5-methylhexanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 7-methyl-3-oxooctanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
|
MetaCyc:
RXN-21649
|
|
|
|
13-methyltetradecanoyl-[acp] + NAD+ <=> (2E)-13-methyltetradec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
|
MetaCyc:
RXN-21667
|
|
|
|
(3R)-3-hydroxy-15-methylhexadecanoyl-[acp] <=> (2E)-15-methylhexadec-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
|
MetaCyc:
RXN-21671
|
|
|
|
11-methyldodecanoyl-[acp] + NAD+ <=> (2E)-11-methyldodec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
|
MetaCyc:
RXN-21662
|
|
|
|
4-methyl-2-oxopentanoate + CoA + NAD+ <=> isovaleryl-CoA + CO2 + NADH
|
1.2.1.25
branched-chain alpha-keto acid dehydrogenase system
1.2.4.4
3-methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)
|
–
–
|
|
BRENDA:
BS231865
KEGG:
R01651
MetaCyc:
2KETO-4METHYL-PENTANOATE-DEHYDROG-RXN
SABIO-RK:
1788
|
|
|
|
9-methyldecanoyl-[acyl-carrier_protein] + NAD+ <=> (2E)-9-methyldec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
|
MetaCyc:
RXN-21657
|
|
|
|
(3R)-3-hydroxy-7-methyloctanoyl-[acp] + NADP+ <=> 7-methyl-3-oxooctanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
|
MetaCyc:
RXN-21650
|
|
|
|
(3R)-3-hydroxy-7-methyloctanoyl-[acp] <=> (2E)-7-methyloct-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
|
MetaCyc:
RXN-21651
|
|
|
|
13-methyltetradecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 15-methyl-3-oxohexadecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
|
MetaCyc:
RXN-21669
|
|
|
|
15-methylhexadecanoyl-[acp] + NAD+ <=> (2E)-15-methylhexadec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
|
MetaCyc:
RXN-21672
|
|
|
|
isovaleryl-CoA + malonyl-[acyl-carrier_protein] + H+ <=> 5-methyl-3-oxohexanoyl-[acp] + CoA + CO2
|
2.3.1.dr
|
–
|
|
MetaCyc:
RXN-21610
|
|
|
|
15-methylhexadecanoyl-[acp] + NADP+ <=> (2E)-15-methylhexadec-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
|
MetaCyc:
RXN-21673
|
|
|
|
(3R)-3-hydroxy-11-methyldodecanoyl-[acp] + NADP+ <=> 11-methyl-3-oxododecanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
|
MetaCyc:
RXN-21660
|
|
|
|
7-methyloctanoyl-[acp] + NAD+ <=> (2E)-7-methyloct-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
|
MetaCyc:
RXN-21652
|
|
|
|
(3R)-3-hydroxy-11-methyldodecanoyl-[acp] <=> (2E)-11-methyldodec-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
|
MetaCyc:
RXN-21661
|
|
|
|
15-methylhexadecanoyl-[acp] + H2O <=> 15-methylhexadecanoate + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
MetaCyc:
RXN-21675
|
|
|
|
(3R)-3-hydroxy-5-methylhexanoyl-[acp] + NADP+ <=> 5-methyl-3-oxohexanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
|
MetaCyc:
RXN-21645
|
|
|
|
(3R)-3-hydroxy-13-methyltetradecanoyl-[acp] <=> (2E)-13-methyltetradec-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
|
MetaCyc:
RXN-21666
|
|
|
|
5-methylhexanoyl-[acp] + NAD+ <=> (2E)-5-methylhex-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
|
MetaCyc:
RXN-21647
|
|
|
|
11-methyldodecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 13-methyl-3-oxotetradecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
|
MetaCyc:
RXN-21664
|
|
|
|
(3R)-3-hydroxy-13-methyltetradecanoyl-[acp] + NADP+ <=> 13-methyl-3-oxotetradecanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
|
MetaCyc:
RXN-21665
|
|
|
|
9-methyldecanoyl-[acyl-carrier_protein] + NADP+ <=> (2E)-9-methyldec-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
|
MetaCyc:
RXN-21658
|
|
|
|
5-methylhexanoyl-[acp] + NADP+ <=> (2E)-5-methylhex-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
|
MetaCyc:
RXN-21648
|
|
|
|
(3R)-3-hydroxy-9-methyldecanoyl-[acp] + NADP+ <=> 9-methyl-3-oxodecanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
|
MetaCyc:
RXN-21655
|
|
|
|
7-methyloctanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 9-methyl-3-oxodecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
|
MetaCyc:
RXN-21654
|
|
|
|
9-methyldecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 11-methyl-3-oxododecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
|
MetaCyc:
RXN-21659
|
|
|
|
13-methyltetradecanoyl-[acp] + H2O <=> 13-methyltetradecanoate + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
|
MetaCyc:
RXN-21715
|
|
|
|
(3R)-3-hydroxy-15-methylhexadecanoyl-[acp] + NADP+ <=> 15-methyl-3-oxohexadecanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
|
MetaCyc:
RXN-21670
|
|
|
|
7-methyloctanoyl-[acp] + NADP+ <=> (2E)-7-methyloct-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
|
MetaCyc:
RXN-21653
|
|
|
|
11-methyldodecanoyl-[acp] + NADP+ <=> (2E)-11-methyldodec-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
|
MetaCyc:
RXN-21663
|
|
|
|
(3R)-3-hydroxy-5-methylhexanoyl-[acp] <=> (2E)-5-methylhex-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
|
MetaCyc:
RXN-21646
|
|
|
|
(3R)-3-hydroxy-9-methyldecanoyl-[acp] <=> (2E)-9-methyldec-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
|
MetaCyc:
RXN-21656
|
|
|
|
L-leucine + 2-oxoglutarate <=> L-glutamate + 4-methyl-2-oxopentanoate
|
2.6.1.1
aspartate transaminase
2.6.1.2
alanine transaminase
2.6.1.39
2-aminoadipate transaminase
2.6.1.42
branched-chain-amino-acid transaminase
2.6.1.57
aromatic-amino-acid transaminase
2.6.1.6
leucine transaminase
2.6.1.67
2-aminohexanoate transaminase
2.6.1.9
histidinol-phosphate transaminase
|
–
–
–
–
–
–
–
–
|
|
BRENDA:
BR47691
KEGG:
R01090
MetaCyc:
BRANCHED-CHAINAMINOTRANSFERLEU-RXN
SABIO-RK:
1352
|
|
|
|
13-methyltetradecanoyl-[acp] + NADP+ <=> (2E)-13-methyltetradec-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
|
MetaCyc:
RXN-21668
|
|