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odd iso-branched-chain fatty acid biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
5-methylhexanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 7-methyl-3-oxooctanoyl-[acp] + CO2 + [acyl-carrier_protein] 2.3.1.179 beta-ketoacyl-[acyl-carrier-protein] synthase II

13-methyltetradecanoyl-[acp] + NAD+ <=> (2E)-13-methyltetradec-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)

(3R)-3-hydroxy-15-methylhexadecanoyl-[acp] <=> (2E)-15-methylhexadec-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase

11-methyldodecanoyl-[acp] + NAD+ <=> (2E)-11-methyldodec-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)

4-methyl-2-oxopentanoate + CoA + NAD+ <=> isovaleryl-CoA + CO2 + NADH 1.2.1.25 branched-chain alpha-keto acid dehydrogenase system
1.2.4.4 3-methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)


9-methyldecanoyl-[acyl-carrier_protein] + NAD+ <=> (2E)-9-methyldec-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)

(3R)-3-hydroxy-7-methyloctanoyl-[acp] + NADP+ <=> 7-methyl-3-oxooctanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase

(3R)-3-hydroxy-7-methyloctanoyl-[acp] <=> (2E)-7-methyloct-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase

13-methyltetradecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 15-methyl-3-oxohexadecanoyl-[acp] + CO2 + [acyl-carrier_protein] 2.3.1.179 beta-ketoacyl-[acyl-carrier-protein] synthase II

15-methylhexadecanoyl-[acp] + NAD+ <=> (2E)-15-methylhexadec-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)

isovaleryl-CoA + malonyl-[acyl-carrier_protein] + H+ <=> 5-methyl-3-oxohexanoyl-[acp] + CoA + CO2 2.3.1.dr

15-methylhexadecanoyl-[acp] + NADP+ <=> (2E)-15-methylhexadec-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)

(3R)-3-hydroxy-11-methyldodecanoyl-[acp] + NADP+ <=> 11-methyl-3-oxododecanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase

7-methyloctanoyl-[acp] + NAD+ <=> (2E)-7-methyloct-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)

(3R)-3-hydroxy-11-methyldodecanoyl-[acp] <=> (2E)-11-methyldodec-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase

15-methylhexadecanoyl-[acp] + H2O <=> 15-methylhexadecanoate + [acyl-carrier_protein] + H+ 3.1.2.14 oleoyl-[acyl-carrier-protein] hydrolase

(3R)-3-hydroxy-5-methylhexanoyl-[acp] + NADP+ <=> 5-methyl-3-oxohexanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase

(3R)-3-hydroxy-13-methyltetradecanoyl-[acp] <=> (2E)-13-methyltetradec-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase

5-methylhexanoyl-[acp] + NAD+ <=> (2E)-5-methylhex-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)

11-methyldodecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 13-methyl-3-oxotetradecanoyl-[acp] + CO2 + [acyl-carrier_protein] 2.3.1.179 beta-ketoacyl-[acyl-carrier-protein] synthase II

(3R)-3-hydroxy-13-methyltetradecanoyl-[acp] + NADP+ <=> 13-methyl-3-oxotetradecanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase

9-methyldecanoyl-[acyl-carrier_protein] + NADP+ <=> (2E)-9-methyldec-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)

5-methylhexanoyl-[acp] + NADP+ <=> (2E)-5-methylhex-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)

(3R)-3-hydroxy-9-methyldecanoyl-[acp] + NADP+ <=> 9-methyl-3-oxodecanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase

7-methyloctanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 9-methyl-3-oxodecanoyl-[acp] + CO2 + [acyl-carrier_protein] 2.3.1.179 beta-ketoacyl-[acyl-carrier-protein] synthase II

9-methyldecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 11-methyl-3-oxododecanoyl-[acp] + CO2 + [acyl-carrier_protein] 2.3.1.179 beta-ketoacyl-[acyl-carrier-protein] synthase II

13-methyltetradecanoyl-[acp] + H2O <=> 13-methyltetradecanoate + [acyl-carrier_protein] + H+ 3.1.2.14 oleoyl-[acyl-carrier-protein] hydrolase

(3R)-3-hydroxy-15-methylhexadecanoyl-[acp] + NADP+ <=> 15-methyl-3-oxohexadecanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase

7-methyloctanoyl-[acp] + NADP+ <=> (2E)-7-methyloct-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)

11-methyldodecanoyl-[acp] + NADP+ <=> (2E)-11-methyldodec-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)

(3R)-3-hydroxy-5-methylhexanoyl-[acp] <=> (2E)-5-methylhex-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase

(3R)-3-hydroxy-9-methyldecanoyl-[acp] <=> (2E)-9-methyldec-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase

L-leucine + 2-oxoglutarate <=> L-glutamate + 4-methyl-2-oxopentanoate 2.6.1.1 aspartate transaminase
2.6.1.2 alanine transaminase
2.6.1.39 2-aminoadipate transaminase
2.6.1.42 branched-chain-amino-acid transaminase
2.6.1.57 aromatic-amino-acid transaminase
2.6.1.6 leucine transaminase
2.6.1.67 2-aminohexanoate transaminase
2.6.1.9 histidinol-phosphate transaminase








13-methyltetradecanoyl-[acp] + NADP+ <=> (2E)-13-methyltetradec-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)

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